Near?Infrared PhotoInitiating Systems: Photothermal versus Triplet–Triplet Annihilation?Based Upconversion Polymerization

نویسندگان

چکیده

NIR light-induced polymerization has attracted more and attention in the photopolymerization field due to possibility use safer penetrating wavelengths, reducing hazardousness. Here, a novel perspective for free radical of acrylate-based monomers based on triplet-triplet annihilation upconversion (TTA-UC) is proposed, avoiding introduction heavy metals, usually required TTA processes. Thermal imaging experiments Fourier transform infrared spectroscopy are respectively used record temperature during irradiation measure reactive function conversion. The competition between TTA-UC photothermal activation investigated compare relative efficiency both In view results obtained by different methods, effect seems get upper hand over photoactivation system.

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ژورنال

عنوان ژورنال: Macromolecular Rapid Communications

سال: 2021

ISSN: ['1022-1336', '1521-3927']

DOI: https://doi.org/10.1002/marc.202100047